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Arctic LTER Database

Acceptance and utilization of LTER data requires that:

(1) The Principal Investigator be sent a notice stating reasons for acquiring any data and a description of the publication intentions.
(2) The Principal Investigator of the data set be sent a copy of the report or manuscript prior to submission and be adequately cited in any resultant publications.
(3) A copy of any resultant publications should be sent to:

Principal Investigator
Ecosystems Center
Marine Biological Laboratory
7 MBL St.
Woods Hole, MA 02543

Older Metadata: Attribute table not in XML (EML) file

Dataset URLs:METADATA: HTML, Rich Text, XML(EML compliant)
DATA: Comma Delimited, Excel file with Metadata and data
Dataset ID:97s7ions
Dataset Title:Measurements of Alkalinity, calcium, magnesium, sodium, potassium, sulfate, and cloride for lake S7 on 23 Jun 1997, Arctic LTER 1997.
Investigator 1: 
First Name:Anne
Last Name:Giblin
Address line 1:
Address line 2:
Address line 3:
City:
State:
Zip Code:
Country:
Associate Investigators:Neil Bettez
Keywords:Alkalinity, Calcium, magnesium, sodium, potassium cations, sulfate, cloride, cations, anions
Abstract: Measurements of Alkalinity, calcium, magnesium, sodium, potassium, sulfate, and cloride for lake S7 on 23 Jun 1997.
Contact: Arctic LTER Information Manager
The Ecosystems Center
Marine Biological Lab
7 MBL St
Woods Hole, MA 02543
Phone (508) 289 7496
Email: arc_im@mbl.edu
Online URL: http://ecosystems.mbl.edu/ARC/
DATA FILE INFORMATION:
Data File Name 97s7ions
Beginning Date 5/1/1997
End Date 9/1/1997
Number of Data Records
Other Files to Reference
Availability Status
Quality Control Information
Maintenance Description
Log of Changes: Log of changes: For Archival Use: DATE RECEIVED: May, 1997 DATA FILE ENTERED BY: Neil Bettez DATA FILE VALIDATION: Neil Bettez NAME: Neil Bettez DATE: May, 1997
RESEARCH LOCATION:
Geographic Description Lake S7
Location Bounding Box
West Bounding Coordinate
East Bounding Coordinate
North Bounding Coordinate
South Bounding Coordinate
OR if single point location
Latitude
Longitude
TAXONOMIC COVERAGE:
Organisms studied
Methods:

Water samples were collected and filtered through a 25mm GFF glass fiber filter. Cation
samples are stored in 60 ml HDPE bottles and are preserved by acidifying to ~ pH 2 (100 ul Ultrex HCL /
60 ml sample. Anion samples are stored in 30 HDPE bottles.

Alkalinity was measured using a Gran titration (Strum and Morgan, 1984).
Cation samples are run on a Perkin Elmer atomic absorption spectrophotometer. Chemical
interference in flame AAS originates during dissociation of the analyte in the flame cell forming a
compound that volatilizes at a different rate than the standard. One method of alleviating this type of
interference is through the addition of a releasing agent or protective chelate. A releasing agent is a metal
or salt that forms a more stable compound with the interferent than the analyte. For calcium analysis the
addition of lanthanum, which acts a releasing agent and reduces interference with the calcium peak from
Al, Si, PO43-, and SO42- is required (Rains, 1984). Lanthanum Cloride (LaCL3 FW 371.38) should be added to a 1% final concentration to all samples and standards. 10% LaCL3 = 37.13 g / liter.
Lanthanum

Anions samples were run on a Dionex 2000 liquid chromatographer using fast sep column.

Reference Citations: Rains, Theodore, C. 1984. Atomic Absorption Spectrometry. Water Analysis, Vol II Edited by Roger A. Minear and Lawrence H. Keith.
Stumm, W. &J. J. Morgan 1981. Aquatic Chemistry , 2nd edition. John Wiley & Sons, New York, 780 pp.
USEPA, 1974. Methods for Chemical analysis of water and wastes. USEPA Washington DC.

Sampling Description.

None

Data Table

Variable		Variable descrip.		Precis./Units		Coded		Missing
(Y/N)		Values
Site code	site code					y
station		sample location					y
I series code	I series code					y
DATE		Date			DD-MMM-YY		n
ALK		Alkalinity				m eqiv/l	n	y
Ca ++		calcium					uM			n
Mg ++		magnesium				uM			n
Na+		sodium					uM			n
K+		potassium				uM			n
SO-4		sulfate					uM			n
Cl		cloride					uM			n
(12) CALCULATIONS
Variable		Formula
uM = (ppm x 1000)/molecular weight of element
K+:  39.1g/mol
Na+: 22.99g/mol
Ca++ : 40.08 g/mol
Mg ++ : 24.31 g/mol

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